Volume 45 Issue 1
Dec.  2022
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LI Yang, ZHANG Jian-liang, YUAN Xiang, LIU Zheng-jian, LI Fei, ZHENG An-yang, LI Zhan-guo. Kinetics and reduction mechanism of non-isothermal analysis carbothermal reduction of zinc ferrite[J]. Chinese Journal of Engineering, 2023, 45(1): 82-90. DOI: 10.13374/j.issn2095-9389.2021.08.05.003
Citation: LI Yang, ZHANG Jian-liang, YUAN Xiang, LIU Zheng-jian, LI Fei, ZHENG An-yang, LI Zhan-guo. Kinetics and reduction mechanism of non-isothermal analysis carbothermal reduction of zinc ferrite[J]. Chinese Journal of Engineering, 2023, 45(1): 82-90. DOI: 10.13374/j.issn2095-9389.2021.08.05.003
shu

Kinetics and reduction mechanism of non-isothermal analysis carbothermal reduction of zinc ferrite

  • 1.

    School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China

  • 2.

    Ironmaking Department of Beijing Shougang Co., Ltd., Tangshan 064404, China

  • 3.

    Ironmaking Department, Xiangtan Iron and Steel Co., Ltd of HuNan VaLin, Xiangtan 411101, China

  • 4.

    Shanxi Jianlong Industry Company, Ltd., Yuncheng 043800, China

More Information
  • Corresponding author:

    LIU Zheng-jian, E-mail: liuzhengjian@ustb.edu.cn

  • Received Date: August 04, 2021
  • Available Online: September 21, 2021
  • Published Date: December 31, 2022
    Graphical Abstract
    • Abstract
  • The amount of zinc-containing EAF dust has increased due to the increased proportion of galvanized steel scrap used in the electric arc furnace (EAF) steelmaking process. If the zinc in the EAF dust is not recycled, it will not only lead to a waste of valuable metal resources but also results in environmental pollution. Zinc is mainly present in the EAF dust in the form of zinc ferrite (ZnFe2O4). Zinc ferrite is a kind of spinel mineral that exhibits a crystal lattice of greater stability, which increases the difficulty of recycling valuable elements such as zinc and iron from zinc-containing EAF dust. To further clarify the carbothermic reduction process of zinc ferrite, this paper studies the kinetics of the non-isothermal carbothermal reduction of zinc ferrite and its reduction reaction mechanism. The phase transition process of the zinc ferrite carbothermal reduction reaction was analyzed via the XRD results of the reduced zinc ferrite. FeO0.85·xZnO was found at 950 °C when Fe3+ was reduced to Fe2+. The relationship between the conversion and conversion rate of the zinc ferrite carbothermal reduction process is discussed. The reduction process can be divided into three stages, and the conversion of the second stage changes greatly (0.085–0.813). Finally, the kinetics of the second stage of the carbothermic reduction of the zinc ferrite at different heating rates was evaluated through the isoconversional method and the master curve fitting method. The activation energy of the second stage is between 331.01–490.04 kJ·mol−1, and the average activation energy is 362.16 kJ·mol−1. The large change in the activation energy in the second stage indicates that the reactions in this stage are more complicated, and there are obvious differences in the activation energy between the reactions. The secondary chemical reaction is the main rate-controlling link in the second stage, and the kinetics equation of the second stage is determined.
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    • References (26)
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