CH4/CO2直接内重整环境下平管型SOFC电堆的稳定性研究

Stability of flat tube SOFC stack with CH4/CO2 direct internal reforming

  • 摘要: 本工作构建了一个由三片平管型固体氧化物电池组成的电池堆,并对氢气和CH4/CO2干重整条件下的电堆发电特性进行了对比分析,探究了CH4/CO2比例和电流密度对电堆瞬时和长期催化重整性能的影响,并分别监测了每片单电池的性能变化。结果显示:在750 °C时,使用氢气燃料与干重整气为燃料的最大放电功率分别为100.0 W与81.1 W,电池堆的非电池部分功率消耗分别为17.6 W和9.8 W。在15 A的恒电流测试中,氢气环境下电池堆在100 h后电压衰减率为0.130‰ h-1;而在CO2/CH4条件下,电池堆在360 h后电压增长率为0.096 ‰ h-1。长期运行中,远离燃料入口的第三片电池是电池堆性能衰减的主要因素。这些发现证实了平管型电池在甲烷干重整过程中具有出色的稳定性。

     

    Abstract: In this work, a stack composed of three flat-tube solid oxide fuel cells (SOFCs) was constructed, and a comparative analysis of the power generation characteristics of the stack under hydrogen and CH4/CO2 dry reforming conditions was conducted. This work investigates the influence of CH4/CO2 ratio and current density on the instantaneous and long-term reforming performance of the stack. Additionally, the performance changes of each individual cell are monitored. The results showed that the maximum power output of the 3-cell stack at 750 °C using hydrogen and dry reforming gas as fuels were 100.0 W and 81.1 W, respectively, with power consumption of the non-cell parts of the stack being 17.6 W and 9.8 W. During a constant current test at 15 A, the stack voltage degradation rate in a hydrogen environment after 100 h of operation was 0.130‰ h-1; under CO2/CH4 conditions, the stack voltage growth rate after 360 h of operation was 0.096 ‰ h-1. During long-term operation, the Cell-3, which is far from the fuel inlet, was the main factor contributing to the performance degradation of the stack. The results indicate the excellent stability of the flat-tube cells in the process of methane dry reforming.

     

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