钛合金化过程对钢液洁净度的影响

Effect of ferro-titanium alloying process on steel cleanness

  • 摘要: 重点考察了Ti合金化过程中影响Ti收得率的主要因素,并对比分析了Ti合金化前后夹杂物的物相变化及夹杂物的去除效果.控制氧活度aO<350×10-6,Al、Ti合金加入时间间隔大于3 min,可以保证Ti收得率>85%;当aO>350×10-6时,需控制Al、Ti合金加入时间间隔为5 min以上.相同aO和Als情况下,延长Al、Ti加入时间间隔可以有效提高Ti收得率.RH处理过程中,钢包内当量直径>200μm的Al2O3夹杂物在5 min内基本可以上浮去除,但相同尺寸的A-Ti-O复合夹杂的去除时间要比Al2O3长1~2 min.Ti合金加入后,Al2O3夹杂物周围会形成Al-Ti-O的复合夹杂,这些夹杂物的形成降低Ti的收得率.

     

    Abstract: The main factors were studied which influence the titanium yield during a ferro-titanium alloying process. The inclusion phases and removal effect were comparatively analyzed before and after ferro-titanium alloying. When controlling the activity of oxygen (ao) before deoxidation below 350×10-6, the interval time between Al and Ti addition above 3 min can guarantee the titanium yield above 85%. With ao above 350×10-6, the interval time between Al and Ti addition should be extended more than 5 min. Extending the interval time between Al and Ti addition can improve the titanium yield at the same ao and Als. During RH refining, Al2O3 inclusions with the equivalent diameter above 200 μm can float and be removed within 5 min, but the removal time of AI-Ti-O inclusions with the same size is 1 to 2 min more than pure Al2O3. Al-Ti-O complex inclusions form around Al2O3 after the titanium alloy being added into the melt, and the titanium yield decreases due to the formation of these inclusions.

     

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